Merck 100056 Acetic Acid (Glacial) EMPROVE® ESSENTIAL Ph Eur, BP, JP, USP, E 260 25 L

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LB.M.100056.9025

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Merck 100056 Acetic Acid (Glacial) EMPROVE® ESSENTIAL Ph Eur, BP, JP, USP, E 260 25 L
Catalogue Number	100056
Synonyms	Ethanoic acid

Merck 100056 Acetic Acid (Glacial) EMPROVE® ESSENTIAL Ph Eur, BP, JP, USP, E 260

Product Information
CAS number	64-19-7
EC index number	607-002-00-6
EC number	200-580-7
Grade	Ph Eur,BP,JP,USP,E 260
Hill Formula	C₂H₄O₂
Chemical formula	CH₃COOH
Molar Mass	60.05 g/mol
HS Code	2915 21 00
Structure formula Image

MERCK 100056 Acetic acid (glacial) %100 suitable for use as excipient EMPROVE® exp Ph Eur, BP, JP, USP, E 260 2.5 L

Physicochemical Information
Boiling point	116 - 118 °C (1013 hPa)
Density	1.05 g/cm3 (20 °C)
Explosion limit	4 - 19.9 %(V)
Flash point	39 °C
Ignition temperature	485 °C
Melting Point	17 °C
pH value	2.5 (50 g/l, H₂O, 20 °C)
Vapor pressure	15.4 hPa (20 °C)
Viscosity kinematic	1.17 mm2/s (20 °C)
Solubility	602.9 g/l soluble

Toxicological Information
LD 50 oral	LD50 Rat 3310 mg/kg

Safety Information according to GHS
Hazard Pictogram(s)
Hazard Statement(s)	H226: Flammable liquid and vapour. H290: May be corrosive to metals. H314: Causes severe skin burns and eye damage.
Precautionary Statement(s)	P210: Keep away from heat. P280: Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
Signal Word	Danger
RTECS	AF1225000
Storage class	3 Flammable liquids
WGK	WGK 1 slightly water endangering
Disposal	4 Liquid organic acids or solutions should be diluted, if necessary, and carefully neutralized with sodium hydrogen carbonate (Cat. No. 106323) or with sodium hydroxide (Cat. No 106462). Before filling into container D, check the pH with pH universal indicator strips (Cat. No. 109535).

Safety Information
Hazard Symbols	Corrosive
Categories of danger	flammable, corrosive
R Phrase	R 10-35 Flammable.Causes severe burns.
S Phrase	S 23-26-45 Do not breathe vapour.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

Storage and Shipping Information
Storage	Store at +15 °C to +25 °C.

Transport Information
Declaration (railroad and road) ADR, RID	UN 2789 , 8 (3), II
Declaration (transport by air) IATA-DGR	UN 2789 , 8 (3), II
Declaration (transport by sea) IMDG-Code	UN 2789 , 8 (3), II, Segregation Group: 1 (Acids)

Specifications
Assay (alkalimetric)	99.8 - 100.5 %
Identity	passes test
Appearance of the substance	passes test
Solidification temperature	≥ 15.6 °C
Foreign organic substances	passes test
Formic acid, Formates and other oxidable impurities (as HCOOH)	≤ 0.10 %
Heavy metals (as Pb)	≤ 0.0005 %
Chloride (Cl)	≤ 0.0002 %
Sulphate (SO₄)	≤ 0.0005 %
Al (Aluminium)	≤ 0.00005 %
As (Arsenic)	≤ 0.00010 %
Cu (Copper)	≤ 0.0005 %
Fe (Iron)	≤ 0.0005 %
Hg (Mercury)	≤ 0.00010 %
Pb (Lead)	≤ 0.00005 %
Zn (Zinc)	≤ 0.0005 %
Other residual solvents (ICH Q3C)	...excluded by production process
Reducing substances (Ph Eur)	passes test
Substances reducing potassium permanganate	passes test
Evaporation residue	≤ 0.005 %
Elemental impurity specifications have been set considering ICH Q3D (Guideline for Elemental Impurities). Class 1-3 elements are not likely to be present above the ICH Q3D option 1 limit, unless specified and indicated (*).
Corresponds to Ph Eur, BP, JP, USP, E260 Conforms to the purity criteria on food additives according to the current European Commission Regulation.

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