Merck 100201 Phenol Suitable EMPROVE® ESSENTIAL Ph Eur, ChP,JP, USP 1 kg

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Diğer Analitik Kimyasallar

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MERCK

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LB.M.100201.1000

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Merck 100201 Phenol Suitable EMPROVE® ESSENTIAL Ph Eur, ChP,JP, USP 1 kg
Catalogue Number	100201
Synonyms	Hydroxybenzene, Carbolic acid

Merck 100201 Phenol Suitable EMPROVE® ESSENTIAL Ph Eur, ChP,JP, USP 2 kg

Product Information
CAS number	108-95-2
EC index number	604-001-00-2
EC number	203-632-7
Grade	Ph Eur,JP,USP
Hill Formula	C₆H₆O
Chemical formula	C₆H₅OH
Molar Mass	94.11 g/mol
HS Code	2907 11 00
Structure formula Image

Physicochemical Information
Boiling point	181.8 °C (1013 hPa)
Density	1.06 g/cm3 (20 °C)
Explosion limit	1.3 - 9.5 %(V)
Flash point	81 °C
Ignition temperature	595 °C
Melting Point	40.8 °C
pH value	5 (50 g/l, H₂O, 20 °C)
Vapor pressure	0.2 hPa (20 °C)
Bulk density	620 kg/m3
Solubility	84 g/l (20 °C)

Toxicological Information
LD 50 dermal	LD50 Rat 660 mg/kg

Safety Information according to GHS
Hazard Pictogram(s)
Hazard Statement(s)	H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled. H314: Causes severe skin burns and eye damage. H341: Suspected of causing genetic defects. H373: May cause damage to organs through prolonged or repeated exposure.
Precautionary Statement(s)	P280: Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
Signal Word	Danger
RTECS	SJ3325000
Storage class	6.1A Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK	WGK 2 water endangering
Disposal	9 Carcinogenic compounds and flammable compounds labelled "Highly toxic" or "Toxic": container F. Alkyl sulfates are carcinogenic; Take particular care to avoid inhalation and skin contact. To neutralize alkyl sulfates, add dropwise (from a dropping funnel) to concentrated ice-cool Ammonia solution (Cat.No. 105426) with vigorous stirring. Before placing in container D, check the pH with pH Universal indicator strips (Cat.No. 109535).

Safety Information
Hazard Symbols	Toxic Corrosive
Categories of danger	toxic, corrosive, mutagenic
R Phrase	R 23/24/25-34-48/20/21/22-68 Toxic by inhalation, in contact with skin and if swallowed.Causes burns.Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.Possible risk of irreversible effects.
S Phrase	S 24/25-26-28-36/37/39-45 Avoid contact with skin and eyes.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.After contact with skin, wash immediately with plenty of soap and water.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

Storage and Shipping Information
Storage	Store at +15 °C to +25 °C.

Transport Information
Declaration (railroad and road) ADR, RID	UN 1671 , 6.1, II
Declaration (transport by air) IATA-DGR	UN 1671 , 6.1, II
Declaration (transport by sea) IMDG-Code	UN 1671 , 6.1, II

Specifications
Specifications
Assay (bromometric)	99.0 - 100.5 %
Assay (bromometric, calc. to dried substance)	99.0 - 100.5 %
Identity (IR-spectrum)	passes test
Identity (coloring 1)	passes test
Identity (coloring 2)	passes test
Identity (precipitate)	passes test
Appearance	colourless or faintly pink or faintly yellowish, crystals or crystalline masses, deliquescent.
Appearance of solution (67 g/l, water)	Clear and not more intensely coloured than reference solution B6
Acidic substances	passes test
Solidification temperature	≥ 39.5 °C
Chloride (Cl)	≤ 0.001 %
Sulphate (SO₄)	≤ 0.005 %
Heavy metals (as Pb)	≤ 0.001 %
Related substances (GC)	passes test
Benzene (HS-GC)	≤ 2 ppm
Methanol (HS-GC)	≤ 3000 ppm
Cumene (HS-GC)	≤ 70 ppm
Residual solvents class 3 (ICH Q3C)	≤ 0.5 %
Other residual solvents (ICH (Q3C))	excluded by manufacturing process
Residue on evaporation	≤ 0.05 %
Water (according to Karl Fischer)	≤ 0.5 %
Residues of metal catalysts or metal reagents acc. to EMEA/C HMP/SWP/4446/2000 are not likely to be present.
Corresponds to Ph Eur, JP, USP

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Merck 100201 Phenol Suitable EMPROVE® ESSENTIAL Ph Eur, ChP,JP, USP 1 kg

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