Merck 100713 Sulfuric Acid 95-98% EMPROVE® ESSENTIAL Ph Eur,BP,JPE,NF CAS No.: 7664-93-9 25 L

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LB.M.100713.9025

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CAS Number: 7664-93-9 EC Number: 231-639-5 Molar Mass: 98.08 g/mol Chemical Formula: H₂SO₄ Hill Formula: H₂O₄S Grade: Ph Eur,BP,JPE,NF View Products on Sigmaaldrich.com 100713 View Pricing & Availability Download Product Safety Card Request More Information About This Product Request a Sample Learn about the Emprove® Program

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Merck 100713 Sulfuric Acid 95-98% EMPROVE^® ESSENTIAL Ph Eur,BP,JPE,NF CAS No.: 7664-93-9
Catalogue Number	100713
Description	Sulfuric acid 95-98%

Product Information
CAS number	7664-93-9
EC index number	016-020-00-8
EC number	231-639-5
Grade	Ph Eur,BP,JPE,NF
Hill Formula	H₂O₄S
Chemical formula	H₂SO₄
Molar Mass	98.08 g/mol
HS Code	2807 00 00
Quality Level	MQ500

Physicochemical Information
Boiling point	335 °C (1013 hPa)
Density	1.84 g/cm3 (20 °C)
Melting Point	-20 °C
pH value	0.3 (49 g/l, H₂O, 25 °C)
Vapor pressure	0.0001 hPa (20 °C)

Safety Information according to GHS
Hazard Pictogram(s)
Hazard Statement(s)	H290: May be corrosive to metals. H314: Causes severe skin burns and eye damage.
Precautionary Statement(s)	P234: Keep only in original packaging. P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Signal Word	Danger
RTECS	WS5600000
Storage class	8B Non-combustible, corrosive hazardous materials
WGK	WGK 1 slightly hazardous to water
Disposal	12 Inorganic acids and anhydrides thereof should first be diluted or hydrolyzed by stirring carefully into ice water and then neutralized (protective gloves, fume cupboard!) with sodium hydroxide solution (Cat. No. 105587). Before filling into container D, check the pH with pH universal indicator strips (Cat. No. 109535). Fuming sulfuric acid should be carefully stirred dropwise into 40 % sulfuric acid (Cat. No. 109286). Ensure that plenty of ice is available for cooling! When sufficiently cool, treat the highly concentrated sulfuric acid as described above. Analogous to this procedure, other anhydrides can be converted into their corresponding acids. Acid gases (e.g. hydrogen halide, chlorine, phosgene, sulfur dioxide) can be introduced into dilute sodium hydroxide solution and after neutralization disposed of in container D.

Safety Information
Categories of danger	corrosive

Storage and Shipping Information
Storage	Store at +2°C to +30°C.

Transport Information
Declaration (railroad and road) ADR, RID	UN 1830 , 8, II
Declaration (transport by air) IATA-DGR	UN 1830 , 8, II
Declaration (transport by sea) IMDG-Code	UN 1830 , 8, II, Segregation Group: 1 (Acids)

Specifications
Assay (alkalimetric)	95.0 - 98.0 %
Identity	passes test
Appearance of solution	passes test
Chloride (Cl)	≤ 0.0002 %
Nitrate (NO₃)	≤ 0.00010 %
Nitrate (NO₃) (Ph Eur)	passes test
As (Arsenic)	≤ 0.000010 %
Fe (Iron)	≤ 0.0002 %
NH₄ (Ammonium)	≤ 0.0005 %
Pb (Lead)	≤ 0.0005 %
V (Vanadium) *	≤ 0.0002
Residual solvents (ICH Q3C)	...excluded by production process
Substances reducing potassium permanganate (as SO₂)	≤ 0.0010 %
Residue on ignition	≤ 0.0050 %
Elemental impurity specifications have been set considering ICH Q3D (Guideline for Elemental Impurities). Class 1-3 elements are not likely to be present above the ICH Q3D option 1 limit, unless specified and indicated (*).
Corresponds to PhEur, BP, JPE, NF Expiry date : see product label
Corresponds to PhEur, BP, JPE, NF Expiry date : see product label

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