Merck 100981 Benzyl alcohol EMPROVE® ESSENTIAL Ph Eur,BP,JP,NF CAS No.: 100-51-6 2.5 L

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LB.M.100981.2500

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CAS Number: 100-51-6 EC Number: 202-859-9 Molar Mass: 108.14 g/mol Chemical Formula: C₆H₅CH₂OH Hill Formula: C₇H₈O Grade: Ph Eur,BP,JP,NF

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MERCK 100981

Merck 100981 Benzyl Alcohol EMPROVE® ESSENTIAL Ph Eur,BP,JP,NF 2.5 L

Description
Catalogue Number	100981
Synonyms	Phenylcarbinol

Product Information
CAS number	100-51-6
EC index number	603-057-00-5
EC number	202-859-9
Grade	Ph Eur,BP,JP,NF
Hill Formula	C₇H₈O
Chemical formula	C₆H₅CH₂OH
Molar Mass	108.14 g/mol
HS Code	2906 21 00
Structure formula Image

Physicochemical Information
Boiling point	205 °C (1013 hPa)
Density	1.05 g/cm3 (20 °C)
Explosion limit	1.3 - 13 %(V)
Flash point	101 °C DIN 51758
Ignition temperature	435 °C DIN 51794
Melting Point	-15.3 °C
Vapor pressure	0.07 hPa (20 °C)
Solubility	40 g/l

Toxicological Information
LD 50 oral	LD50 Rat 1620 mg/kg

Safety Information according to GHS
Hazard Statement(s)	H302 + H332: Harmful if swallowed or if inhaled. H319: Causes serious eye irritation.
Precautionary Statement(s)	P271: Use only outdoors or in a well-ventilated area. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Signal Word	Warning
RTECS	DN3150000
Storage class	10 - 13 Other liquids and solids
WGK	WGK 1 slightly hazardous to water
Disposal	3 Relatively unreactive organic reagents should be collected in container A. If halogenated, they should be collected in container B. For solid residues use container C.

Safety Information
Categories of danger	harmful
R Phrase	R 20/22 Harmful by inhalation and if swallowed.
S Phrase	S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Storage and Shipping Information
Storage	Store at +2 °C to +25 °C.

Transport Information
Declaration (railroad and road) ADR, RID	Kein Gefahrgut
Declaration (transport by air) IATA-DGR	UN 3334 , 9, III
Declaration (transport by sea) IMDG-Code	No Dangerous Good

Specifications
Assay (GC)	98.0 - 100.5 %
Identity (IR)	conforms
Appearance of solution (nephelometric)	conforms
Clarity of solution	conforms
Color of solution	conforms
Acidity	conforms
Refractive index (n 20/D)	1.538 - 1.541
Density (d 20 °C/20 °C)	1.043 - 1.049
Peroxide value	≤ 5.0
Related substances (GC) (Benzaldehyde (Impurity A))	≤ 0.15 %
Related substances (GC) (Cyclohexylmethanol (Impurity B))	≤ 0.10 %
Related substances (GC) (Sum of peaks with a relative retention less than that of benzyl alcohol)	≤ 0.04 %
Related substances (GC) (Sum of peaks with a relative retention greater than that of benzyl alcohol)	≤ 0.3 %
Related substances (GC) (disregard limit)	≤ 0.0001 %
Benzene (GC)	≤ 0.0002 %
Chlorobenzene (GC)	≤ 0.01 %
Toluene (GC)	≤ 0.01 %
Other residual solvents (ICH Q3C)	excluded by manufacturing process
Evaporation residue	≤ 0.050 %
Water	≤ 0.10 %
Elemental impurity specifications have been set considering ICH Q3D (Guideline for Elemental impurities). Class 1-3 elements are not likely to be present above the ICH Q3D option 1 limit, unless specified and indicated (*). Conforms to Ph Eur, BP, JP, NF

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