Merck 102790 Copper(II) sulfate pentahydrate for analysis EMSURE® ACS,ISO,Reag. Ph Eur 50 kg

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MERCK

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LB.M.102790.9050

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Synonyms: Copper monosulfate pentahydrate, Copper vitriol pentahydrate CAS Number: 7758-99-8 EC Number: 231-847-6 Molar Mass: 249.68 g/mol Chemical Formula: CuSO₄ * 5 H₂O Hill Formula: CuO₄S * 5 H₂O Grade: ACS,ISO,Reag. Ph Eur

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Merck 102790

Copper(II) sulfate pentahydrate for analysis EMSURE® ACS, ISO, Reag. Ph Eur

Description
Catalogue Number	102790
Replaces	CX2185-20
Synonyms	Copper monosulfate pentahydrate, Copper vitriol pentahydrate

Product Information
CAS number	7758-99-8
EC index number	029-004-00-0
EC number	231-847-6
Grade	ACS,ISO,Reag. Ph Eur
Hill Formula	CuO₄S * 5 H₂O
Chemical formula	CuSO₄ * 5 H₂O
Molar Mass	249.68 g/mol
HS Code	2833 25 00

Physicochemical Information
Density	2.284 g/cm3 (20 °C)
pH value	3.5 - 4.5 (50 g/l, H₂O, 20 °C)
Solubility	317 g/l (20 °C)

Toxicological Information
LD 50 oral	LD50 Rat 960 mg/kg
LD 50 dermal	LD50 Rat > 2000 mg/kg

Safety Information according to GHS
Hazard Pictogram(s)
Hazard Statement(s)	H302: Harmful if swallowed. H315: Causes skin irritation. H319: Causes serious eye irritation. H410: Very toxic to aquatic life with long lasting effects.
Precautionary Statement(s)	P273: Avoid release to the environment. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Signal Word	Warning
RTECS	GL8900000
Storage class	10 - 13 Other liquids and solids
WGK	WGK 3 highly water endangering
Disposal	15 Heavy metal-containing solutions and solids: container E. Stir Raney nickel (also: Urushibara nickel) in the form of an aqueous suspension into hydrochloric acid (Cat. No. 100312) until dissolved (container E). Neither Raney nickel itself nor any filter residues should be allowed to dry out, otherwise they will spontaneously ignite in air. In this context, heavy metal means any compound of antimony, arsenic, cadmium, chromium(VI), copper, lead, nickel and tin, as well as these subtances in metallic form, if they are classified as hazardous (acc. to AbfallverzeichnisV - Waste Catalogue Ordinance, Appendix 3). Other heavy metals should be collected separately.

Safety Information
Hazard Symbols	Harmful Dangerous for the environment
Categories of danger	harmful, irritant, dangerous for the environment
R Phrase	R 22-36/38-50/53 Harmful if swallowed.Irritating to eyes and skin.Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S Phrase	S 22-60-61 Do not breathe dust.This material and its container must be disposed of as hazardous waste.Avoid release to the environment. Refer to special instructions/ Safety data sheets.

Storage and Shipping Information
Storage	Store at +5°C to +30°C.

Transport Information
Declaration (railroad and road) ADR, RID	UN 3077 Umweltgefährdender Stoff, fest, n.a.g.(KUPFER(II)-SULFAT), 9, III
Declaration (transport by air) IATA-DGR	UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.(COPPER(II)-SULPHATE), 9, III
Declaration (transport by sea) IMDG-Code	UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.(COPPER(II)-SULPHATE), 9, III, Marine Pollutant: P, Segregation Group: 7 (Heavy metals and their salts (including their organometallic compounds))

Specifications
Specifications
Assay (iodometric)	99.0 - 100.5 %
Insoluble matter	≤ 0.005 %
Chloride (Cl)	≤ 0.0005 %
Total nitrogen (N)	≤ 0.001 %
Ca (Calcium)	≤ 0.005 %
Fe (Iron)	≤ 0.003 %
K (Potassium)	≤ 0.001 %
Na (Sodium)	≤ 0.005 %
Ni (Nickel)	≤ 0.005 %
Pb (Lead)	≤ 0.005 %
Zn (Zinc)	≤ 0.03 %
Corresponds to ACS,ISO,Reag. Ph Eur

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