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Sigma-Aldrich 208566 Titanium(IV) chloride ReagentPlus®, 99.9% trace metals basis CAS No.: 7550-45-0 1.5 kg
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LB.SA.208566-1.5KG
Kısa Bilgi
Synonym(s): TTC, Titanium tetrachloride Linear Formula: TiCl4 CAS Number: 7550-45-0 Molecular Weight: 189.68 EC Number: 231-444-5 MDL number: MFCD00011267 UNSPSC Code: 12352300 PubChem Substance ID: 329752044 NACRES: NA.55 Assay: 99.9% trace metals basis Form: liquid
| Sigma-Aldrich 208566 Titanium(IV) chloride ReagentPlus®, 99.9% trace metals basis |
| Synonym(s): TTC, Titanium tetrachloride Linear Formula: TiCl4 CAS Number: 7550-45-0 Molecular Weight: 189.68 EC Number: 231-444-5 MDL number: MFCD00011267 UNSPSC Code: 12352300 PubChem Substance ID: 329752044 NACRES: NA.55 Assay: 99.9% trace metals basis Form: liquid |
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PROPERTIES
vapor pressure 50 mmHg ( 55 °C), 9.6 mmHg ( 20 °C)
Quality Level 200 product line ReagentPlus® Assay 99.9% trace metals basis form liquid reaction suitability reagent type: catalyst, core: titanium bp 135-136 °C (lit.) mp −25 °C (lit.) density 1.73 g/mL at 20 °C (lit.) SMILES string Cl[Ti](Cl)(Cl)Cl InChI 1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4 InChI key XJDNKRIXUMDJCW-UHFFFAOYSA-J DESCRIPTION General description Titanium(IV) chloride participates in the Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone.[1] Neutral solutions of TiCl4 having a pH in the range of 2.5 to 6.0 (prepared by the addition of magnesium oxide as a base) have been used for the synthesis of nanosized titanium dioxide.[2] Application Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines.[3] Along with sodium borohydride, it forms an effective reagent for the reduction of:[4] - carboxylic acid and acyl chloride to alcohols - carboxamides, oximes and lactams to amines - sulfoxides to sulfides Titanium(IV) chloride (TiCl4) has been used as a precursor for the synthesis of Ag-TiO2@polyethylene glycol (PEG) nanoparticles.[5] TiCl4 may also be used as one of the constituents to synthesize TiO2/Al2O3 binary oxide materials[6] and N-(10-oxo-vinylanthracen-9-(10H)-ylidene)cyanamide.[7] Legal Information ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany |
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