Sigma-Aldrich 357405 Zirconium(IV) chloride ≥99.9% trace metals basis 10 gr
Kategori
Marka
Stok Kodu
LB.SA.357405-10G
Kısa Bilgi
Synonym(s): Tetrachlorozirconium, Zirconium tetrachloride, Linear Formula: ZrCl4, CAS Number: 10026-11-6, Molecular Weight: 233.04, EC Number: 233-058-2
| Sigma-Aldrich 357405 Zirconium(IV) chloride ≥99.9% trace metals basis 10 gr |
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Synonym(s): Tetrachlorozirconium, Zirconium tetrachloride
Linear Formula: ZrCl4
CAS Number: 10026-11-6
Molecular Weight: 233.04
EC Number: 233-058-2
MDL number: MFCD00011306
PubChem Substance ID: 24861912
NACRES: NA.23
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PROPERTIES
vapor pressure 1 mmHg (190 °C)
Quality Level 100
assay ≥99.9% trace metals basis
form powder
reaction suitability reagent type: catalyst, core: zirconium
impurities ≤1000.0 ppm
Trace Metal Analysis
transition temp sublimation point 331 °C
density 2.8 g/mL at 25 °C (lit.)
application(s) battery manufacturing
SMILES string Cl[Zr](Cl)(Cl)Cl
InChI 1S/4ClH.Zr/h4*1H;/q;;;;+4/p-4
InChI key DUNKXUFBGCUVQW-UHFFFAOYSA-J
DESCRIPTION
Aplication
Zirconium (IV) chloride acts as an efficient Lewis acid catalyst for various reactions; such as:
electrophilic addition reaction of indole with aldehydes/ketones to form bis(indolyl)methanes. electrophilic amination of activated arenes,
transthioacetylization of acetals,
deoxygenation of heterocyclic-N-oxides,
reduction of nitro compounds, conversion of carbonyl compounds to 1,3-oxathiolanes,
Biginelli reaction for the synthesis of 3,4-dihydropyrimidin-2(1H)-ones,
direct amide coupling of non activated carboxylic acids and amines, synthesis of quinoxalines and pyrido[2,3-b]pyrazines, deprotection of t-butyldimethylsilyl (TBDMS) ethers.
Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines.
Packaging
10, 100 g in glass bottle
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