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Sigma-Aldrich 386529 Chlorotrimethylsilane purified by redistillation, ≥99% CAS No.: 75-77-4 1 L
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LB.SA.386529-1L
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Synonym(s): TMSCl, TMCS, Trimethylchlorosilane, Trimethylsilyl chloride Linear Formula: (CH3)3SiCl CAS Number: 75-77-4 Molecular Weight: 108.64 UNSPSC Code: 12352302 NACRES: NA.22 PubChem Substance ID: 24864097 EC Number: 200-900-5 Beilstein/REAXYS Number: 1209232 MDL number: MFCD00000502 Assay: ≥99% Form: liquid
| Sigma-Aldrich 386529 Chlorotrimethylsilane purified by redistillation, ≥99% CAS No.: 75-77-4 |
| Synonym(s): TMSCl, TMCS, Trimethylchlorosilane, Trimethylsilyl chloride Linear Formula: (CH3)3SiCl CAS Number: 75-77-4 Molecular Weight: 108.64 UNSPSC Code: 12352302 NACRES: NA.22 PubChem Substance ID: 24864097 EC Number: 200-900-5 Beilstein/REAXYS Number: 1209232 MDL number: MFCD00000502 Assay: ≥99% Form: liquid |
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PROPERTIES
Product Name Chlorotrimethylsilane, purified by redistillation, ≥99%
InChI key IJOOHPMOJXWVHK-UHFFFAOYSA-N InChI 1S/C3H9ClSi/c1-5(2,3)4/h1-3H3 SMILES string C[Si](C)(C)Cl vapor density 3.7 (vs air) vapor pressure 100 mmHg ( 25 °C) assay ≥99% form liquid autoignition temp. 752 °F purified by glass distillation redistillation expl. lim. 6.4 % impurities <0.1% dichlorodimethylsilane refractive index n20/D 1.387 (lit.) bp 57 °C (lit.) mp −40 °C (lit.) density 0.856 g/mL at 25 °C (lit.) Quality Level 200 DESCRIPTION Application Chlorotrimethylsilane (TMSCl) can be used as: - A reagent to protect alcohol and amine groups via the formation of trimethylsilyl ethers and trimethylsilyl amines.[1][2] - A catalyst for the preparation of 1,3-diphenyl-2-propenone derivatives (chalcones) as antimicrobial agents.[2] - A trapping agent for the anions generated during acyloin condensation reaction.[3] - A better alternative catalyst to the toxic mercuric chloride for the activation of samarium (Sm) during the cyclopropanation of both allylic and α-allenic alcohols.[4] - A catalyst in the transesterification of triglycerides with alcohols to form fatty acid alkyl esters.[5] - A reagent along with lithium bromide for the conversion of alcohols to the corresponding bromides.[6] - A reagent in Fischer glycosidation.[7] - A source of acid catalyst in the reductive benzylation reaction using benzaldehyde and Et3SiH.[8] - A reagent to synthesize sodium trimethylsilanethiolate (Me3SiSNa) by reacting with sodium sulfide, which is an odorless alternative method of synthesizing Me3SiSNa from foul-smelling bis(trimethylsilyl)sulfide and sodium methoxide.[9] General description Chlorotrimethylsilane is a chloroorganosilane compound mainly used for silylation reactions.[10] |
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